Silver-Prompted Carbonitration of Acrylamides for the Synthesis of Nitrating Oxindoles

Xiao-Hong Wei; Quan-Xiang Wu; Shang-Dong Yang

doi:10.1055/s-0034-1380514

Synlett, Table of Contents

Synlett 2015; 26(10): 1417-1421
DOI: 10.1055/s-0034-1380514

letter

Silver-Prompted Carbonitration of Acrylamides for the Synthesis of Nitrating Oxindoles

Authors

Xiao-Hong Wei

^aState Key Laboratory of Applied Organic Chemistry, Lanzhou University, Lanzhou 730000, P. R. of China
Quan-Xiang Wu

^aState Key Laboratory of Applied Organic Chemistry, Lanzhou University, Lanzhou 730000, P. R. of China
Shang-Dong Yang*

^aState Key Laboratory of Applied Organic Chemistry, Lanzhou University, Lanzhou 730000, P. R. of China

^bState Key Laboratory for Oxo Synthesis and Selective Oxidation, Lanzhou Institute of Chemical Physics, Chinese Academy of Sciences, Lanzhou 730000, P. R. of China Email: yangshd@lzu.edu.cn

Abstract

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Abstract

A silver-prompted carbonitration of alkenes involving concomitant direct C–H functionalization and C–N bond formation to synthesize nitrating oxindoles has been developed. The CR TH2 receptor antagonist skeleton can be obtained from one of the products with further modification.

Key words

silver - N-methyl-N-arylacrylamide - carbonitration - nitrating oxindoles

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Supplementary Material

Supporting Information (PDF)